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2022-01-12
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How to Cite
Study on catalytic properties of graphene/molybdenum sulfide under near-infrared light irradiation
Huan Zhang
School of Chemistry, Biology and Materials Engineering, Suzhou University of Science and Technology Jiangsu Key Laboratory of Environmental Functional Materials
Shouqing Liu
School of Chemistry, Biology and Materials Engineering, Suzhou University of Science and Technology Jiangsu Key Laboratory of Environmental Functional Materials
DOI: https://doi.org/10.24294/ace.v5i1.1402
Keywords: G/MoS2, Hybrid Catalyst, Near-Infrared Light, Photocatalysis
Abstract
Graphene/MoS2 hybrid material was prepared by the hydrothermal method. The hybrid material was characterized by X-ray diffraction spectrum, Raman spectra, transmission electron microscope and UV-vis-NIRS. It was used as a near-infrared photocatalyst to catalyze and degrade Rhodamine B (RhB). The results showed that when the concentration of the RhB solution was 50.0 mg·L–1, the pH value of the solution was 7, the volume of the solution was 50.0 mL, the amount of G/MoS2 catalyst was 0.05 g and near-infrared radiation was carried out for 3 h, the degradation rate of RhB in the 50 mL solution reached 96.5%. When MoS2 was used as the photocatalyst, the degradation rate of RhB was only 75.5%. After 5 times of recycling, the catalytic efficiency of the hybrid photocatalyst was still more than 90%, indicating that the catalyst is very stable.References
[1] Fujishima A, Honda K. Electrochemical photolysis of water at a semiconductor electrode. Nature 1972; 238(5358): 37–38.[2] Carey JH, Lawrence J, Tosine HM. Photodechlorination of PCB’s in the presence of titanium dioxide in aqueous suspensions. Bulletin of Environmental Contamination and Toxicology 1976; 16(6): 697–701.
[3] Hoffmann MR, Martin S, Choi W, et al. Environmental applications of semiconductor photocatalysis. Chemical Reviews 1995; 95(1): 69–96.
[4] Rimeh D, Patrick D, Didier R. Modified TiO2 for environmental photocatalytic applications: A review. Industrial & Engineering Chemistry Research 2013; 52(10): 3581–3599.
[5] Banerjee S, Pillai SC, Falaras P, et al. New insights into the mechanism of visible light photocatalysis. Journal of Physical Chemistry Letters 2014; 5(15): 2543–2554.
[6] Maneesha M, Doo-man C. α-Fe2O3 as a photocatalytic material: A review. Applied Catalysis A: General 2015; 498(5): 126–141.
[7] He R, Cao S, Zhou P, et al. Recent advances in visible light Bi-based photocatalysts. Chinese Journal of Catalysis 2014; 35(7): 989–1007.
[8] Wei D, Yao L, Yang S, et al. Band gap Engineering of In2TiO5 for H2 production under nearinfrared light. ACS Applied Mater Interfaces 2015; 7(37): 20761–20768.
[9] Zhang X, Yu L, Zhuang C, et al. Highly asymmetric phthalocyanine as a sensitizer of graphitic carbon nitride for extremely efficient photocatalytic H2 production under near-infrared light. ACS Catalysis 2013; 4(1): 162–170.
[10] Tang Y, Di W, Zhai X, et al. NIR-responsive photocatalytic activity and mechanism of NaYF4:Yb, Tm@TiO2 core-shell nanoparticles. ACS Catalysis 2013; 3(3): 405–412.
[11] Li H, Liu R, Liu Y, et al. Carbon quantum dots/Cu2O composites with protruding nanostructures and their highly efficient (near) infrared photocatalytic behavior. Journal of Materials Chemistry 2012; 22(34): 17470–17475.
[12] Zhang Y, Liang Y, Zhou J. Recent progress of graphene doping. Acta Chimica Sinica 2014; 72(3): 367–377.
[13] Shen C, Zhang J, Shi D, et al. Photoluminescence enhancement in monolayer molybdenum disulfide by annealing in air. Acta Chimica Sinica 2015; 73(9): 954–958.
[14] Shi J, Ma D, Zhang Y, et al. Controllable growth of MoS2 on Au foils and its application in hydrogen evolution. Acta Chimica Sinica 2015; 73(9): 877–885.
[15] Chang K, Mei Z, Wang T, et al. MoS2/graphene cocatalyst for efficient photocatalytic H2 evolution under visible light irradiation. ACS Nano 2014; 8(7): 7078–7087.
[16] Zong X, Wu G, Yan H, et al. Photocatalytic H2 evolution on MoS2/CdS catalysts under visible light irradiation. Journal of Physical Chemistry C 2010; 114(4): 1963–1968.
[17] Zong X, Yan H, Wu G, et al. Enhancement of photocatalytic H2 evolution on CdS by loading MoS2 as cocatalyst under visible light irradiation. Journal of the Amercan Chemical Society 2008; 130(23): 7176–7177.
[18] Yang L, Zhong D, Zhang J, et al. Optical properties of metal-molybdenum disulfide hybrid nanosheets and their application for enhanced photocatalytic hydrogen evolution. ACS Nano 2014; 8(7): 6979–6985.
[19] Li Y, Wang H, Peng S. Tunable photodeposition of MoS2 onto a composite of reduced graphene oxide and CdS for synergic photocatalytic hydrogen generation. The Journal of Physical Chemistry C 2014; 118(34): 19842–19848.
[20] Xiang Q, Yu J, Jaroniec M. Synergetic effect of MoS2 and graphene as cocatalysts for enhanced photocatalytic H2 production activity of TiO2 nanoparticles. Journal of the American Chemical Society 2012; 134(15): 6575–6578.
[21] Min S, Lu G. Sites for high efficient photocatalytic hydrogen evolution on a limited-layered MoS2 cocatalyst confined on graphene sheets—The role of graphene. Journal of Physical Chemistry C 2012; 116(48): 25415–25424.
[22] Yin W, Yan L, Yu J, et al. High-throughput synthesis of single-layer MoS2 nanosheets as a near-infrared photothermal-triggered drug delivery for effective cancer therapy. ACS Nano 2014; 8(7): 6922–6933.
[23] Mak KF, Lee CG, Hone J, et al. Atomically thin MoS2: A new direct-gap semiconductor. Physical Review Letters 2010; 105(13): 474–479.
[24] Noorden VR. Moving towards a graphene world. Nature 2006; 442(7100): 228–229.
[25] Stolyarova E, Rim KT, Ryu SM, et al. High-resolution scanning tunneling microscopy imaging of mesoscopic graphene sheets on an insulating surface. Proceedings of the National Academy of Sciences of the United States of America 2007; 104(22): 9209–9212.
[26] Novoselov KS, Geim AK, Morozov SV, et al. Two-dimensional gas of massless diracfermions in grapheme. Nature 2005; 438(7065): 197–200.
[27] Tian Y, He Y, Shang J, et al. Hydrothermal synthesis and characterization of laminar MoS2. Acta Chimica Sinica 2004; 62(18): 1807–1810.
[28] Xu Y, Sheng K, Li C, et al. Self-assembled graphene hydrogel via a one-step hydrothermal process. ACS Nano 2010; 4(7): 4324–4330.
[29] Shen J, Li T, Long Y, et al. One-step solid state preparation of reduced graphene oxide. Carbon 2012; 50(6): 2134–2140.
[30] Zhou Y, Bao Q, Tang LAL, et al. Hydrothermal dehydration for the “green” reduction of exfoliated graphene oxide to graphene and demonstration of tunable optical limiting properties. Chemistry of Materials 2009; 21(13): 2950–2956.
[31] Wu H, Yang R, Song B, et al. Biocompatible inorganic fullerene-like molybdenum disulfide nanoparticles produced by pulsed laser ablation in water. ACS Nano 2011; 5(2): 1276–1281.
[32] Stankovich S, Dikin DA, Piner RD, et al. Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide. Carbon 2007; 45(7): 1558–1565.