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2023-07-06
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Photodegradation of Methylene blue and Rhodamine B using potato starch mediated zinc oxide nanoparticles and its calcium nanocomposites: Greener approach
Darshan Singh
University of Delhi
Anuradha Anuradha
University of Delhi
Surendra Kumar
University of Delhi
Amar Kumar
Patliputra University
Neelu Dheer
University of Delhi
M. Ramananda Singh
University of Delhi
Rajni Kanojia
University of Delhi
Sangeeta Kaul
University of Delhi
Ishwar Prasad Sahu
Indira Gandhi National Tribal University
DOI: https://doi.org/10.24294/ace.v6i1.1998
Keywords: ZnO NPs, Ca-ZnO Nanocomposites, Potato Starch, Methylene Blue, Rhodamine B
Abstract
Zinc oxide is considered an effective photocatalyst for degradation of several organic contaminants found in wastewater. This work reports the biological synthesis of zinc oxide nanoparticles and its calcium nanocomposites to study the photocatalytic deterioration of two dyes, viz. Rhodamine B and Methylene blue, under natural sunlight. Nanoparticles were synthesized using zinc acetate and starch extracted from potato at pH 7–8. Potato starch acts as both a capping agent and a reducing agent. They were characterized spectroscopically via XRD, SEM, HR-TEM, EDAX and FT-IR techniques. Bean/spherical shaped ZnO NPs were obtained in the size range of 29–49 nm whereas calcium coating on ZnO decreased the particle size, i.e., 25–35 nm. Their photocatalytic ability to degrade Rhodamine B and Methylene blue was studied under natural sunlight and monitored using UV-Vis spectrophotometer. Synthesized ZnO nanoparticles and its calcium coated ZnO nanocomposites showed promising results in degradation of these dyes. Methylene blue was completely degraded in an hour at 8 mg of the sample. Although degradation of Rhodamine dye was slow, synthesized samples were effective catalysts as compared to the ones reported in the literature.
Author Biography
Ishwar Prasad Sahu, Indira Gandhi National Tribal University
Dr. Ishwar Prasad Sahu received the B.Sc. degree in Mathematics, Physics and Computer Science in 2006 and the M.Sc. degree in Physics in 2008, both from the Pt. Ravishankar Shukla University, Raipur, Chhattisgath, India. He also received the M. Phil. degree in 2009 from Dr. C.V. Raman University, Bilaspur, Chhattisgarh, India and receive Ph.D. degree in Physics in 2015 from Pt. Ravishankar Shukla University, Raipur, Chhattisgarh, India. The title of his thesis was “Studies on the Luminescence Properties of Rare Earth Doped Silicate Based Long Afterglow Phosphors.” His research interest is in the field of Material Science. His research works mainly include the Luminescence behavior of rare earth-doped aluminates, silicates, ortho-silicate, oxide etc., based phosphors materials. This is designed to be an invaluable academic contribution in the field of Material Science. After the completion of Doctoral degree he joined School of Studies in Physics & Astrophysics, Pt. Ravishankar Shukla University, Raipur, Chhattisgarh, India in 2016 as a Assistant Professor (On Contract). After that he joined Department of Physics, Indira Gandhi National Tribal University, Lalpur - Amarkantak, Anuppur, Madhya Pradesh, India as Assistant Professor. He has more than a 70 publications in the field of material science at Peer-reviewed (International and National) Journals And, he has around 30 conference presentations to his credit. He is Serving as a journal peer reviewer is one of the most important duties in the scientific profession. He received prestigious Prof. B. P. Chandra research award for outstanding research contribution in the field of Luminescence by Luminescence Society of India (LSI). He is also Lifetime member (580) of Luminescence Society of India (LSI).
References
1.Samuchiwal S, Gola D, Malik A. Decolourizationof textile effluent using native microbial consortium enriched from textile industry effluent. Journalof Hazardous Materials 2021; 402: 123835. doi:10.1016/j.jhazmat.2020.123835.2.Bansal M, Patnala PK, Dugmore T. Adsorption ofEriochrome Black-T(EBT) using tea waste as a low cost adsorbent by batch studies: A green approach for dye effluent treatments. Current Research in Green and Sustainable Chemistry 2020; 3: 100036. doi: 10.1016/j.crgsc.2020.100036.
3.Nazir MA, Bashir MS, Jamshaid M, et al. Synthesisof porous secondary metal-doped MOFs for removal of Rhodamine B from water: Role of secondary metal on efficiency and kinetics. Surfaces and Interfaces 2021; 25: 101261. doi: 10.1016/j.surfin.2021.101261.
4.Wang S, Zhu ZH. Characterisation and environmental application of an Australian natural zeolite for basic dye removal from aqueous solution. Journal of Hazardous Materials 2006; 136(3): 946–952. doi: 10.1016/j.jhazmat.2006.01.038.
5.Wan D, Li W, Wang G, et al. Adsorption and heterogeneous degradation of Rhodamine B on the surface of magnetic bentonite material. Applied Surface Science 2015; 349: 988–996. doi: 10.1016/j.apsusc.2015.05.004.
6.Sinha T, Ahmaruzzaman M, Bhattacharjee A. A simple approach for the synthesis of silver nanoparticles and their application as a catalyst for thephotodegradation of methyl violet 6B dye under solar irradiation. Journal of Environmental ChemicalEngineering 2014; 2(4): 2269–2279. doi: 10.1016/j.jece.2014.10.001.
7.Sinha T, Ahmaruzzaman M. High-value utilizationof egg shell to synthesize Silver and Gold−Silvercore shell nanoparticles and their application forthe degradation of hazardous dyes from aqueousphase—A green approach. Journal of Colloidand Interface Science 2015; 453: 115–131. doi:10.1016/j.jcis.2015.04.053.
8.Ahmad A, Mohd-Setapar SH, Chuong CS, et al. Recent advances in new generation dye removal technologies: Novel search for approaches to reprocesswastewater. RSC Advances 2015; 5: 30801–30818.doi: 10.1039/c4ra16959j.
9.Dong S, Feng J, Fan M, et al. Recent developmentsin heterogeneous photocatalytic water treatmentusing visible light-responsive photocatalysts: A review. RSC Advances 2015; 5: 14610–14630. doi:10.1039/C4RA13734E.
10.Nazir MA, Khan NA, Cheng C, et al. Surfaceinduced growth of ZIF-67 at Co-layered doublehydroxide: Removal of Methylene blue and methylorange from water. Applied Clay Science 2020;190: 105564. doi: 10.1016/j.clay.2020.105564.
11.Nazir MA, Najam T, Shahzad K, et al. Heterointerface engineering of water stable ZIF-8@ZIF-67: Adsorption of Rhodamine B from water. Surfaces and Interfaces 2022; 34: 102324. doi: 10.1016/j.surfin.2022.102324.
12. Nazir MA, Nazam T, Jabeen S, et al. Facile synthesis of tri-metallic layered double hydroxides (NiZnAl-LDHs): Adsorption of Rhodamine-B and methyl orange from water. Inorganic Chemistry Communications 2022; 145: 110008. doi: 10.1016/j.inoche.2022.110008.
13. Momeni MM. Study of synergistic effect among photo-, electro-, and sonoprocesses in photocatalyst degradation of phenol on tungsten-loaded titania nanotubes composite electrode. Applied Physics A: Materials Science and Processing 2015; 119: 1413–1422. doi: 10.1007/s00339-015-9114-3.
14. Liqiang J, Yichun Q, Baiqi W, et al. Review of photoluminescence performance of nano-sized semiconductor materials and its relationships with photocatalytic activity. Solar Energy Materials and Solar Cells 2006; 90(12): 1773–1787. doi: 10.1016/j.solmat.2005.11.007.
15. Mahlambi MM, Ngila CJ, Mamba BB. Recent developments in environmental photocatalytic degradation of organic pollutants: The case of titanium dioxide nanoparticles—A review. Journal of Nanomaterials 2015; 2015: 790173. doi: 10.1155/2015/790173.
16. Ruszkiewicz JA, Pinkas A, Ferrer B, et al. Neurotoxic effect of active ingredients in sunscreen products, a contemporary review. Toxicology Reports 2017; 4: 245–259. doi: 10.1016/j.toxrep.2017.05.006.
17. Guy N, Çakar S, Ozacar M. Comparison of palladium/zinc oxide photocatalysts prepared by different palladium doping methods for congo red degradation. Journal of Colloid and Interface Science 2016; 466: 128–137. doi: 10.1016/j.jcis.2015.12.009.
18. Rodrigues J, Hatami T, Rosa JM, et al. Photocatalytic degradation using ZnO for the treatment of RB 19 and RB 21 dyes in industrial effluents and mathematical modeling of the process. Chemical Engineering Research and Design 2020; 153: 294–305. doi: 10.1016/j.cherd.2019.10.021.
19. Liu H, Hu Y, Zhang Z, et al. Synthesis of spherical Ag/ZnO heterostructural composites with excellent photocatalytic activity under visible light and UV irradiation. Applied Surface Science 2015; 355: 644–652. doi: 10.1016/j.apsusc.2015.07.012.
20. Ul-Haq AN, Nadhman A, Ullah I, et al. Synthesis approaches of zinc oxide nanoparticles: The dilemma of ecotoxicity. Journal of Nanomaterials 2017; 2017: 8510342. doi: 10.1155/2017/8510342.
21. Bandeira M, Giovanela M, Roesch-Ely M, et al. Green synthesis of zinc oxide nanoparticles: A review of the synthesis methodology and mechanism of formation. Sustainable Chemistry and Pharmacy 2020; 15: 100223. doi: 10.1016/j.scp.2020.100223.
22. Mallakpour S, Madani M. Use of silane coupling agent for surface modification of zinc oxide as inorganic filler and preparation of poly(amide–imide)/zinc oxide nanocomposite containing phenylalanine moieties. Bulletin of Materials Science 2012; 35(3): 333–339. doi: 10.1007/s12034-012-0304-8.
23. Ma J, Zhu W, Tian Y, et al. Preparation of zinc oxide-starch nanocomposite and its application on coating. Nanoscale Research Letters 2016; 11: 200. doi: 10.1186/s11671-016-1404-y.
24. Mehmood A, Murtaza G, Bhatti TM, et al. Phyto-mediated synthesis of silver nanoparticles from Melia azedarach L. leaf extract: Characterization and antibacterial activity. Arabian Journal of Chemistry 2017; 10(2): S3048–S3053. doi: 10.1016/j.arabjc.2013.11.046.
25. Renault F, Morin-Crini N, Gimbert F, et al. Cationized starch-based materials a new ion-exchanger adsorbent for the removal of C.I. Acid Blue 25 from aqueous solutions. Bioresource Technology 2008; 99(16): 7573–7586. doi: 10.1016/j.biortech.2008.02.011.
26. Chen Q, Yu H, Wang L, et al. Recent progress in chemical modification of starch and its applications. RSC Advances 2015; 5: 67459–67474. doi: 10.1039/c5ra10849g.
27. Sree GV, Nagaraaj P, Kalanidhi K, et al. Calcium oxide a sustainable photocatalyst derived from eggshell for efficient photo-degradation of organic pollutants. Journal of Cleaner Production 2020; 270: 122294. doi: 10.1016/j.clepro.2020.122294.
28. Osuntokun J, Onwudiwe DC, Ebenso EE. Aqueous extract of broccoli mediated synthesis of CaO nanoparticles and its application in the photocatalytic degradation of bromocresol green. IET Nanobiotechnology 2018; 12(7): 888–894. doi: 10.1049/iet-nbt.2017.0277.
29. Gopalappa H, Yogendra K, Mahadevan KM, et al. A comparative study on the solar photocatalytic degradation of brilliant red azo dye by CaO and CaMgO2 nanoparticles. International Journal of Science and Research 2012; 1: 91–95. doi: 10.13140/RG.2.2.24749.95204.
30. Thakur S, Singh S, Pal B. Time-dependent growth of CaO nano flowers from egg shells exhibit improved adsorption and catalytic activity. Advanced Powder Technology 2021; 32: 3288–3296. doi: 10.1016/j.apt.2021.07.015.
31. Buazara F, Bavi M, Kroushawi F, et al. Potato extract as reducing agent and stabiliser in a facile green one-stepsynthesis of ZnO nanoparticles. Journal of Experimental Nanoscience 2016; 11(3): 175–184. doi: 10.1080/17458080.2015.1039610.
32. Singh D, Anuradha, Mathur D, et al. Photocatalytic properties of biologically synthesized uncoated and calcium coated ZnO nanoparticles using cucumber juice. Rasayan Journal of Chemistry 2022; Special Issue: 95–102. doi: 10.31788/RJC.2022.1558177.
33. Huang Y, Lyu LM, Lin CY, et al. Improved mass-transfer enhances photo-driven dye degradation and H2 evolution over a few-layer WS2/ZnO heterostructure. ACS Omega 2022; 7(2): 2217–2223. doi: 10.1021/acsomega.1c05756.
34. Daman TC, Porto SPS, Tell B. Raman effect in zinc oxide. Physical Review 1981; 142: 570. doi: 10.1103/PhysRev.142.570.
35. Richter H, Wang ZP, Ley L. The one phonon Raman spectrum in microcrystalline silicon. Solid State Communications 1981; 39(5): 625–629. doi: 10.1016/0038-1098(81)90337-9.
36. Abebe B, Zereffa EA, Murthy HCA. Synthesis of poly(vinyl alcohol)-aided ZnO/Mn2O3 nanocomposites for acid orange-8 dye degradation: Mechanism and antibacterial activity. ACS Omega 2021; 6(1): 954–964. doi: 10.1021/acsomega.0c05597.
37. Pham TAT, Tran VA, Le VD, et al. Facile preparation of ZnO nanoparticles and Ag/ZnO nanocomposite and their photocatalytic activities under visible light. International Journal of Photoenergy 2020; 2020: 8897667. doi: 10.1155/2020/8897667.
38. Yontar AK, Avcioglu S, Cevik S. Nature-based nanocomposites for adsorption and visible light photocatalytic degradation of Methylene blue dye. Journal of Cleaner Production 2022; 380: 135070. doi: 10.1016/j.jclepro.2022.135070.
39. Muruganandham M, Swaminathan M. Photocatalytic decolorization and degradation of reactive orange 4 by TiO2-UV process. Dyes and Pigments 2006; 68(2–3): 133–142. doi: 10.1016/j.dyepig.2005.01.004.
40. Al Hamedi FH, Rauf MA, Ashraf SS. Degradation studies of Rhodamine B in the presence of UV/H2O2. Desalination 2009; 239(1–3): 159–166. doi: 10.1016/j.desal.2008.03.016.
41. Batra V, Kaur I, Pathania D, et al. Efficient dye degradation strategies using green synthesized ZnO-based nanoplatforms: A review. Applied Surface Science Advances 2022; 11: 100314. doi: 10.1016/j.apsadv.2022.100314.
42. Jeffrey A, Nethravathi C, Rajamathi M. Nitrogen-doped alkylamine-intercalated layered titanates for photocatalytic dye degradation. ACS Omega 2019; 4(1): 1575–1580. doi: 10.1021/acsomega.8b03207.
43. Vijayan K, Vijayachamundeeswari SP. Improving the multifunctional attributes and photocatalytic dye degradation of MB and RhB dye—A comparative scrutiny. Inorganic Chemistry Communications 2022; 144: 109940. doi: 10.1016/j.inoche.2022.109940.
44. Gul R, Sharma P, Kumar R, et al. A sustainable approach to the degradation of dyes by fungal species isolated from industrial wastewaters: Performance, parametric optimization, kinetics and degradation mechanism. Environmental Research 2023; 216: 114407. doi: 10.1016/j.envres.2022.114407.
45. Shaheen I, Ahmed KS, Thomas A, et al. Phytogenic synthesis and enhanced photocatalytic properties of ZnOCo3O4 p-n junction: Biomimetic water remediators. Ionics 2022; 28: 1999–2006. doi: 10.1007/s11581-021-04407-0.
46. Abhilash MR, Akshatha G, Srikantaswamy S. Photocatalytic dye degradation and biological activities of the Fe2O3/Cu2O nanocomposite. RSC Advances 2019; 9: 8557–8568. doi: 10.1039/C8RA09929D.
47. Vo HT, Nguyen AT, Tran CV, et al. Self-assembly of porphyrin nanofibers on ZnO nanoparticles for the enhanced photocatalytic performance for organic dye degradation. ACS Omega 2021; 6: 23203–23210. doi: 10.1021/acsomega.1c02808.
48. Reddy NR, Reddy PM, Jung JH, et al. Construction of various morphological ZnO-NiO S-scheme nanocomposites for photocatalytic dye degradation. Inorganic Chemistry Communications 2022; 146: 110107. doi: 10.1016/j.inoche.2022.110107.