Published
2026-06-11
Issue
Section
Review Article
License
Copyright (c) 2026 Irene Nindita Pradnya, Widi Astuti, Rafeqah Raslan, Maharani Kusumaningrum, Maulida Zakia, Resna Auliyah Hasanah, Nadifa Alya Fauziah

This work is licensed under a Creative Commons Attribution 4.0 International License.
The Author(s) warrant that permission to publish the article has not been previously assigned elsewhere.
Author(s) shall retain the copyright of their work and grant the Journal/Publisher right for the first publication with the work simultaneously licensed under:
OA - Creative Commons Attribution-NonCommercial 4.0 International (CC BY-NC 4.0). This license allows for the copying, distribution and transmission of the work, provided the correct attribution of the original creator is stated. Adaptation and remixing are also permitted.

This license intends to facilitate free access to, as well as the unrestricted reuse of, original works of all types for non-commercial purposes.
How to Cite
Sustainable biowaste activated carbons for cleaner wastewater treatment by adsorption: A review
Irene Nindita Pradnya
Department of Chemical Engineering, Universitas Negeri Semarang, Semarang, 50229, Indonesia
Widi Astuti
Department of Chemical Engineering, Universitas Negeri Semarang, Semarang, 50229, Indonesia
Rafeqah Raslan
School of Chemical Engineering, College of Engineering, Universiti Teknologi Mara, Selangor Darul Ehsan, 40450, Malaysia
Maharani Kusumaningrum
Department of Chemical Engineering, Universitas Negeri Semarang, Semarang, 50229, Indonesia
Maulida Zakia
Department of Chemical Engineering, Universitas Negeri Semarang, Semarang, 50229, Indonesia
Resna Auliyah Hasanah
Department of Chemical Engineering, Universitas Negeri Semarang, Semarang, 50229, Indonesia
Nadifa Alya Fauziah
Department of Chemical Engineering, Universitas Negeri Semarang, Semarang, 50229, Indonesia
DOI: https://doi.org/10.59429/ace.v9i2.5926
Keywords: activated carbon; adsorption; biomass; circular economy; waste; wastewater treatment
Abstract
The rapid expansion of industrial activities alongside the depletion of natural resources has intensified the global demand for sustainable wastewater treatment technologies. Activated carbon derived from biowaste precursors presents a superior eco-friendly and economically viable alternative to conventional fossil-based materials while advancing the strategic goals of a circular economy. This comprehensive review evaluates synthesis pathways encompassing conventional and hydrothermal carbonization, physical and chemical activation mechanisms, and the technical advantages offered by microwave-assisted heating. Systematic synthesis of literature demonstrates that biowaste-based activated carbon possesses exceptional morphological characteristics and adsorption capacities that frequently surpass commercial standards for the remediation of synthetic dyes, heavy metals, and pharmaceutical contaminants. Despite these advancements, this review identifies a critical research gap regarding the persistent difficulty in standardizing final product quality due to the inherent chemical and structural variability of diverse biomass precursors. Furthermore, the lack of performance evaluation in multi-component pollutant systems fails to accurately reflect the complex chemical interactions of real-world industrial wastewater streams. This fundamental discrepancy between controlled experimental success and rigorous industrial requirements continues to be the primary obstacle preventing the widespread implementation of biowaste-derived adsorbents.
References
[1]. L. Lin, H. Yang, and X. Xu, “Effects of Water Pollution on Human Health and Disease Heterogeneity: A Review,” Front. Environ. Sci., vol. 10, p. 880246, Jun. 2022, doi: 10.3389/FENVS.2022.880246/BIBTEX.
[2]. S. Kato and Y. Kansha, “Comprehensive review of industrial wastewater treatment techniques,” Environ. Sci. Pollut. Res. 2024 3139, vol. 31, no. 39, pp. 51064–51097, Aug. 2024, doi: 10.1007/S11356-024-34584-0.
[3]. I. Zahoor and A. Mushtaq, “Water Pollution from Agricultural Activities: A Critical Global Review,” IJCBS, vol. 23, no. 1, p. 2023, 2023, Accessed: Aug. 01, 2025. [Online]. Available: www.iscientific.org/Journal.html
[4]. H. Abu Hasan, M. H. Muhammad, and N. I. Ismail, “A review of biological drinking water treatment technologies for contaminants removal from polluted water resources,” J. Water Process Eng., vol. 33, p. 101035, Feb. 2020, doi: 10.1016/J.JWPE.2019.101035.
[5]. M. Varol and C. Tokatlı, “Evaluation of the water quality of a highly polluted stream with water quality indices and health risk assessment methods,” Chemosphere, vol. 311, p. 137096, Jan. 2023, doi: 10.1016/J.CHEMOSPHERE.2022.137096.
[6]. S. S. Sonone, S. Jadhav, M. S. Sankhla, and R. Kumar, “Water Contamination by Heavy Metals and their Toxic Effect on Aquaculture and Human Health through Food Chain,” Lett. Appl. NanoBioScience, vol. 10, no. 2, pp. 2148–2166, 2021, doi: 10.33263/LIANBS102.21482166.
[7]. V. Saxena, “Water Quality, Air Pollution, and Climate Change: Investigating the Environmental Impacts of Industrialization and Urbanization,” Water. Air. Soil Pollut., vol. 236, no. 2, pp. 1–40, Feb. 2025, doi: 10.1007/S11270-024-07702-4/TABLES/5.
[8]. S. Wong, N. Ngadi, I. M. Inuwa, and O. Hassan, “Recent advances in applications of activated carbon from biowaste for wastewater treatment: A short review,” J. Clean. Prod., vol. 175, pp. 361–375, Feb. 2018, doi: 10.1016/J.JCLEPRO.2017.12.059.
[9]. G. Palani et al., “Current Trends in the Application of Nanomaterials for the Removal of Pollutants from Industrial Wastewater Treatment—A Review,” Mol. 2021, Vol. 26, Page 2799, vol. 26, no. 9, p. 2799, May 2021, doi: 10.3390/MOLECULES26092799.
[10]. H. N. Tran, “Adsorption Technology for Water and Wastewater Treatments,” Water 2023, Vol. 15, Page 2857, vol. 15, no. 15, p. 2857, Aug. 2023, doi: 10.3390/W15152857.
[11]. J. Y. Lai and L. H. Ngu, “Comparative laboratory cost analysis of various activated carbon activation process,” IOP Conf. Ser. Mater. Sci. Eng., vol. 1195, no. 1, p. 012018, Oct. 2021, doi: 10.1088/1757-899X/1195/1/012018.
[12]. M. Danish and T. Ahmad, “A review on utilization of wood biomass as a sustainable precursor for activated carbon production and application,” Renew. Sustain. Energy Rev., vol. 87, no. February, pp. 1–21, 2018, doi: 10.1016/j.rser.2018.02.003.
[13]. G. K. Gupta, D. Pandey, H. Liu, N. Kango, and P. Shukla, “Sustainable technologies for bio-waste utilization and valorization: perspectives and challenges,” Biomass and Bioenergy, vol. 199, p. 107941, Aug. 2025, doi: 10.1016/J.BIOMBIOE.2025.107941.
[14]. A. Irshad, B. Ali, M. Imran, M. Atif, I. Ahmed, and M. Alex, “Thermo-chemical strategies to prepare biowaste derived activated carbon as metal adsorbent,” Adsorption, vol. 30, no. 8, pp. 2135–2174, Dec. 2024, doi: 10.1007/S10450-024-00499-Y/TABLES/4.
[15]. A. Tyagi, S. Banerjee, S. Singh, and K. K. Kar, “Biowaste derived activated carbon electrocatalyst for oxygen reduction reaction: Effect of chemical activation,” Int. J. Hydrogen Energy, vol. 45, no. 34, pp. 16930–16943, Jul. 2020, doi: 10.1016/J.IJHYDENE.2019.06.195.
[16]. J. Guo et al., “Reduction and Reuse of Forestry and Agricultural Bio-Waste through Innovative Green Utilization Approaches: A Review,” For. 2024, Vol. 15, Page 1372, vol. 15, no. 8, p. 1372, Aug. 2024, doi: 10.3390/F15081372.
[17]. P. Pal et al., “Circular Bioeconomy in Action: Transforming Food Wastes into Renewable Food Resources,” Foods 2024, Vol. 13, Page 3007, vol. 13, no. 18, p. 3007, Sep. 2024, doi: 10.3390/FOODS13183007.
[18]. H. A. Aziz and H. R. A. M. Y. D. A. A. F. M. Noor, “Sequential treatment for stabilized landfill leachate by ozonation – adsorption and adsorption – ozonation methods,” Int. J. Environ. Sci. Technol., vol. 18, no. 4, pp. 861–870, 2021, doi: 10.1007/s13762-020-02891-x.
[19]. J. Song, L. Zhu, S. Yu, G. Li, and D. Wang, “The synergistic effect of adsorption and Fenton oxidation for organic pollutants in water remediation : an overview,” pp. 33489–33511, 2024, doi: 10.1039/d4ra03050h.
[20]. M. N. B, “International Journal of Coal Geology Structure and morphology of chars and activated carbons obtained from thermal treatment of coal and biomass origin materials , including their wastes : Results from the ICCP Microscopy of Carbon Materials Working Grou,” vol. 288, no. May, 2024, doi: https://doi.org/10.1016/j.coal.2024.104519.
[21]. K. Zhang et al., “Effects of the Pore Structure of Commercial Activated Carbon on the Electrochemical Performance of Supercapacitors,” EST, vol. 45, no. September 2021, p. 103457, 2022, doi: 10.1016/j.est.2021.103457.
[22]. K. Sun et al., “Microporous activated carbons from coconut shells produced by self-activation using the pyrolysis gases produced from them , that have an excellent electric double layer performance,” New Carbon Mater., vol. 32, no. 5, pp. 451–459, 2017, doi: 10.1016/S1872-5805(17)60134-3.
[23]. R. Sakthivel, M. A. R, R. Aruna, T. F. G, R. Rizwana, and S. Abinaya, “Harnessing the Potential of Coconut Shell Activated Carbon and Nitrogen-Doped Activated Carbon-Catalysts for Sustainable Power Generation ( A-Review ),” 2024, doi: 10.13005/ojc/400226.
[24]. P. P. Anoop and T. Palanisamy, “Coconut shell biochar – Bacillus cereus DKBovi-5 based biocomposite as a sustainable additive for cement mortar : Effect of pyrolysis temperature on characterization , strength , hydration , and healing,” Sustain. Chem. Pharm., vol. 46, no. May, p. 102112, 2025, doi: 10.1016/j.scp.2025.102112.
[25]. S. H. Tang, N. A. R. Lim, and H. Yeong, “Advancing biomass-based activated carbon production: challenges, techniques, and opportunities with focus on Malaysia,” 2025, doi: https://doi.org/10.1007/s10668-025-05998-8.
[26]. H. Hussain, S. Muhammad, A. Francesco, P. Erasmo, M. Anaiz, and G. Fareed, “AGRICULTURAL BIOMASS REUSE AND TRANSFORMATION AND ITS APPLICATION Overview of environmental and economic viability of activated carbons derived from waste biomass for adsorptive water treatment applications,” Environ. Sci. Pollut. Res., no. 0123456789, 2023, doi: 10.1007/s11356-023-30540-6.
[27]. I. Bukhari, F. Haq, M. Kiran, T. Aziz, S. Mehmood, and M. Haroon, “Biomass and Bioenergy Lignocellulosic biomass as a renewable resource : Driving second-generation biofuel innovation from agricultural waste,” Biomass and Bioenergy, vol. 201, no. March, p. 108133, 2025, doi: 10.1016/j.biombioe.2025.108133.
[28]. L. Kuzwayo, L. Qwabe, P. Nosizo, and P. Ntola, “Journal of Hazardous Materials Advances A review of the current status of removal of endocrine disruptive estrogens from wastewater using lignocellulosic biomass-derived adsorbents,” J. Hazard. Mater. Adv., vol. 19, no. July, p. 100826, 2025, doi: 10.1016/j.hazadv.2025.100826.
[29]. M. Clauser, G. Gonz, C. M. Mendieta, J. Kruyeniski, and C. Area, “Biomass Waste as Sustainable Raw Material for Energy and Fuels,” 2021, doi: https://doi.org/10.1016/B978-0-443-29210-1.00070-4.
[30]. J. Lee, S. Lee, and D. Lee, “Technology Current status and future prospects of biological routes to bio-based products using raw materials, wastes, and residues as renewable resources,” Crit. Rev. Environ. Sci. Technol., vol. 52, no. 14, pp. 2453–2509, 2022, doi: 10.1080/10643389.2021.1880259.
[31]. H. A. Areti, A. S. Hamda, L. D. Abo, and A. Jabesa, “Biowastes as sustainable catalysts for water treatment: A comprehensive overview,” Environ. Adv., vol. 19, no. December 2024, p. 100610, 2025, doi: 10.1016/j.envadv.2025.100610.
[32]. A. M. Elgarahy, M. G. Eloffy, A. Alengebawy, D. Aboelela, A. Hammad, and K. Z. Elwakeel, “Journal of Environmental Chemical Engineering Biowaste valorization: Integrating circular economy principles with artificial intelligence-driven optimization for sustainable energy solutions,” vol. 13, no. October 2024, 2025, doi: https://doi.org/10.1016/j.jece.2025.116673.
[33]. A. Oladipo, O. Ejeromedoghene, O. Kehinde, V. Enwemiwe, and K. Azubuike, “Next Sustainability Waste-to-fuel: The potentials of waste hard nutshell oil and biowaste heterogeneous catalysts for biodiesel production,” Next Sustain., vol. 6, no. March, p. 100145, 2025, doi: 10.1016/j.nxsust.2025.100145.
[34]. W. He, Z. Ni, M. Liu, M. Cui, L. Shi, and Y. Zhao, “Journal of Analytical and Applied Pyrolysis Evaluation of four preparation methods and electrochemical properties of walnut shell-based activated carbon,” J. Anal. Appl. Pyrolysis, vol. 192, no. May, p. 107315, 2025, doi: 10.1016/j.jaap.2025.107315.
[35]. T. T. Nadew, “Synthesis of activated carbon from banana peels for dye removal of an aqueous solution in textile industries: optimization, kinetics, and isotherm aspects,” vol. 18, no. 4, pp. 947–966, 2023, doi: 10.2166/wpt.2023.042.
[36]. K. S. Ukanwa, K. Patchigolla, R. Sakrabani, E. Anthony, and S. Mandavgane, “A Review of Chemicals to Produce Activated Carbon from Agricultural Waste Biomass,” pp. 1–35, 2019.
[37]. F. Althoey, O. Z. Id, and K. M. Elhadi, Sulfate activation of wheat straw ash to enhance the properties of high-performance concrete with recycled aggregates and waste tire steel fibers. 2024. doi: 10.1371/journal.pone.0311838.
[38]. F. Benstoem et al., “Elimination of micropollutants by activated carbon produced from fi bers taken from wastewater screenings using hydrothermal carbonization,” J. Environ. Manage., vol. 211, pp. 278–286, 2018, doi: 10.1016/j.jenvman.2018.01.065.
[39]. G. Abulikemu et al., “Role of grinding method on granular activated carbon characteristics,” Carbon Trends, vol. 11, no. November 2022, p. 100261, 2023, doi: 10.1016/j.cartre.2023.100261.
[40]. W. Li, K. Yang, J. Peng, L. Zhang, S. Guo, and H. Xia, “Effects of carbonization temperatures on characteristics of porosity in coconut shell chars and activated carbons derived from carbonized coconut shell chars,” vol. 8, pp. 190–198, 2008, doi: 10.1016/j.indcrop.2008.02.012.
[41]. R. Kumar, B. Singh, and B. Acharya, “A comprehensive review on activated carbon from pyrolysis of lignocellulosic biomass: An application for energy and the environment,” Carbon Resour. Convers., vol. 7, no. 4, p. 100228, 2024, doi: 10.1016/j.crcon.2024.100228.
[42]. J. De Smedt, P. J. Arauzo, and F. Ronsse, “Journal of Analytical and Applied Pyrolysis Molten salts vs conventional activating agents for activated carbon production: A comprehensive review,” J. Anal. Appl. Pyrolysis, vol. 192, no. April, p. 107239, 2025, doi: 10.1016/j.jaap.2025.107239.
[43]. S. Chen, Z. Liu, S. Jiang, and H. Hou, “Science of the Total Environment Carbonization: A feasible route for reutilization of plastic wastes,” Sci. Total Environ., vol. 710, p. 136250, 2020, doi: 10.1016/j.scitotenv.2019.136250.
[44]. Y. Hendronursito, W. Astuti, H. Sabarman, and I. Santoso, “A porous activated carbon derived from banana peel by hydrothermal activation two-step methods,” vol. 14, no. 2, pp. 322–331, 2025, doi: https://doi.org/10.61435/ijred.2025.60847.
[45]. W. Meng, L. Zheng, S. Cheng, and Z. Li, “Unlocking sustainable opportunities for sludge-derived aqueous phase via hydrothermal carbonization,” Renew. Sustain. Energy Rev., vol. 224, no. September 2024, p. 116084, 2025, doi: 10.1016/j.rser.2025.116084.
[46]. S. Bas and S. S. Baran, “Hydrothermal carbonization of various lignocellulosics: Fuel characteristics of hydrochars and surface characteristics of activated hydrochars,” vol. 100, pp. 259–268, 2019, doi: 10.1016/j.wasman.2019.09.021.
[47]. A. J. R. De Castro et al., “Vibrational Spectroscopy Ordered porous carbons from hydrothermally treated biomass: Effects of the thermal treatments on the structure and porosity,” Vib. Spectrosc., vol. 111, no. April, p. 103175, 2020, doi: 10.1016/j.vibspec.2020.103175.
[48]. N. R. Yogamalar, A. Chithambararaj, and D. B. Mathi, “Advancing sustainability through biomass-derived carbon activation for high porosity and surface area in electrochemical capacitance,” J. Power Sources, vol. 647, no. January, p. 237324, 2025, doi: 10.1016/j.jpowsour.2025.237324.
[49]. K. Kishibayev, B. Dziejarski, R. Tokpayev, and T. Khavaza, “Production of activated carbons from corn cobs waste by steam or H 3 PO 4 activation for effective CO 2 capture and industrial gas selectivity,” vol. 404, no. April 2025, 2026, doi: 10.1016/j.fuel.2025.136266.
[50]. M. Rathnayaka and H. Sitinamaluwa, “Electrochimica Acta Graphene oxide / Activated carbon nano composite with hierarchical pore structure for supercapacitor applications,” Electrochim. Acta, vol. 517, no. January, p. 145752, 2025, doi: 10.1016/j.electacta.2025.145752.
[51]. R. Vanshpati and A. Kumar, “The Critical Role of Chemical Activation in Synthesizing High ‑ Performance Porous Activated Carbon: Turning Waste into Wealth,” Korean J. Chem. Eng., no. 0123456789, 2025, doi: 10.1007/s11814-025-00523-z.
[52]. N. L. Panwar, “Influence of activation conditions on the physicochemical properties of activated biochar: a review,” pp. 925–947, 2022, doi: https://doi.org/10.1007/s13399-020-00870-3.
[53]. O. Ioannidou and A. Ã. Zabaniotou, “Agricultural residues as precursors for activated carbon production — A review,” vol. 11, pp. 1966–2005, 2007, doi: 10.1016/j.rser.2006.03.013.
[54]. W. Wonago, K. Nigus, G. Habtu, M. Kassahun, A. Zenamarkos, and B. Sendekie, “Advances in various pretreatment strategies of lignocellulosic substrates for the production of bioethanol: a comprehensive review,” Discov. Appl. Sci., 2025, doi: 10.1007/s42452-025-06748-1.
[55]. L. Ni, S. R. Juliastuti, and M. Mahfud, “Microwave-Assisted Synthesis , Characterization , and Performance Assessment of Lemongrass-Derived Activated Carbon for Removal of Fe and Mn from Acid,” pp. 1–22, 2025, doi: 10.32604/jrm.2025.02025-0044.
[56]. W. Ao et al., “Microwave assisted preparation of activated carbon from biomass : A review,” Renew. Sustain. Energy Rev., vol. 92, no. July 2017, pp. 958–979, 2018, doi: 10.1016/j.rser.2018.04.051.
[57]. L. Ni, S. R. Juliastuti, and M. Mahfud, “One-stage microwave-assisted activated carbon preparation from Langsat peel raw material for adsorption of iron , manganese and copper from acid mining waste,” vol. 8, no. 2, pp. 143–153, 2023, doi: https://doi.org/10.21924/cst.8.2.2023.1299.
[58]. T. Michałek et al., “Adsorption of Au ( III ), Pt ( IV ), Pd ( II ), and Rh ( III ) ions on activated carbon in a batch reactor supported by microwave radiation,” no. Iii, pp. 1–18, 2025, doi: https://doi.org/10.1038/s41598-025-89990-2.
[59]. Z. Zhang, W. Qu, J. Peng, L. Zhang, and X. Ma, “Comparison between microwave and conventional thermal reactivations of spent activated carbon generated from vinyl acetate synthesis,” DES, vol. 249, no. 1, pp. 247–252, 2009, doi: 10.1016/j.desal.2009.03.008.
[60]. M. Song et al., “Journal of Colloid and Interface Science Biowaste-based porous carbon for supercapacitor: The influence of preparation processes on structure and performance,” J. Colloid Interface Sci., vol. 535, pp. 276–286, 2019, doi: 10.1016/j.jcis.2018.09.055.
[61]. L. Mingzhe et al., “Carbon Capture Science & Technology Biochar production, activation, and applications: A comprehensive technical review,” vol. 16, no. December 2024, 2025, doi: 10.1016/j.ccst.2025.100421.
[62]. X. Li, Z. Hua, Z. Li, M. Shao, F. Lü, and P. J. He, “Preparation and Application of Hierarchical Porous Carbon Materials from Waste and Biomass: A Review,” Waste and Biomass Valorization, vol. 12, no. 4, pp. 1699–1724, 2021, doi: 10.1007/s12649-020-01109-y.
[63]. W. Spencer, G. Senanayake, M. Altarawneh, D. Ibana, and A. N. Nikoloski, “Review of the effects of coal properties and activation parameters on activated carbon production and quality,” Miner. Eng., vol. 212, no. February, p. 108712, 2024, doi: 10.1016/j.mineng.2024.108712.
[64]. Z. Raji, A. Karim, A. Karam, and S. Khalloufi, “Adsorption of Heavy Metals: Mechanisms, Kinetics, and Applications of Various Adsorbents in Wastewater Remediation — A Review,” pp. 775–805, 2023, doi: https://doi.org/10.3390/waste1030046.
[65]. C. Samdan and H. Demiral, “Enrichment of the surface functional groups of activated carbon by modification method,” vol. 22, no. December 2020, 2021, doi: 10.1016/j.surfin.2020.100873.
[66]. W. Zhang et al., “Microwave-enhanced synthesis of magnetic porous covalent triazine-based framework composites for fast separation of organic dye from aqueous solution,” J. Hazard. Mater., vol. 186, no. 2–3, pp. 984–990, 2011, doi: 10.1016/j.jhazmat.2010.11.093.
[67]. M. Farhan Hanafi and N. Sapawe, “A review on the water problem associate with organic pollutants derived from phenol, methyl orange, and remazol brilliant blue dyes,” Mater. Today Proc., vol. 31, pp. A141–A150, Jan. 2020, doi: 10.1016/J.MATPR.2021.01.258.
[68]. P. M. Kapanga et al., “A review of dye effluents polluting African surface water: sources, impacts, physicochemical properties, and treatment methods,” Discov. Water 2024 41, vol. 4, no. 1, pp. 1–27, Oct. 2024, doi: 10.1007/S43832-024-00129-2.
[69]. A. Various, B. Likozar, and A. K. D Alsukaibi, “Various Approaches for the Detoxification of Toxic Dyes in Wastewater,” Process. 2022, Vol. 10, Page 1968, vol. 10, no. 10, p. 1968, Sep. 2022, doi: 10.3390/PR10101968.
[70]. H. Kolya and C. W. Kang, “Toxicity of Metal Oxides, Dyes, and Dissolved Organic Matter in Water: Implications for the Environment and Human Health,” Toxics 2024, Vol. 12, Page 111, vol. 12, no. 2, p. 111, Jan. 2024, doi: 10.3390/TOXICS12020111.
[71]. M. Konwar and R. Rani Boruah, “Textile Industry and Its Environmental Impacts: A Review,” J. Pure App. Biosci, vol. 8, no. 3, pp. 134–139, 2020, doi: 10.18782/2582-2845.7848.
[72]. G. Bal and A. Thakur, “Distinct approaches of removal of dyes from wastewater: A review,” Mater. Today Proc., vol. 50, pp. 1575–1579, Jan. 2022, doi: 10.1016/J.MATPR.2021.09.119.
[73]. Z. Heidarinejad, M. H. Dehghani, M. Heidari, G. Javedan, I. Ali, and M. Sillanpää, “Methods for preparation and activation of activated carbon: a review,” Environ. Chem. Lett. 2020 182, vol. 18, no. 2, pp. 393–415, Jan. 2020, doi: 10.1007/S10311-019-00955-0.
[74]. E. D. Huang Kong et al., “Recent advances in titanium dioxide bio-derived carbon photocatalysts for organic pollutant degradation in wastewater,” iScience, vol. 28, no. 5, May 2025, doi: 10.1016/J.ISCI.2025.112368.
[75]. I. Khan et al., “Review on Methylene Blue: Its Properties, Uses, Toxicity and Photodegradation,” Water 2022, Vol. 14, Page 242, vol. 14, no. 2, p. 242, Jan. 2022, doi: 10.3390/W14020242.
[76]. N. L. Panwar and A. Pawar, “Influence of activation conditions on the physicochemical properties of activated biochar: a review,” Biomass Convers. Biorefinery, vol. 12, no. 3, pp. 925–947, Mar. 2022, doi: 10.1007/S13399-020-00870-3/FIGURES/4.
[77]. H. Yang et al., “Insight into the formation mechanism of N, P co-doped mesoporous biochar from H3PO4 activation and NH3 modification of biomass,” Fuel Process. Technol., vol. 230, p. 107215, Jun. 2022, doi: 10.1016/J.FUPROC.2022.107215.
[78]. E. Science, “Exploring The Environmental Implications of Phosphoric Acid Manufacturing : Database Study Exploring The Environmental Implications of Phosphoric Acid Manufacturing : Database Study,” 2025, doi: 10.1088/1755-1315/1505/1/012005.
[79]. B. Huang et al., “Effect of ZnCl2, H3PO 4, and KOH activation on low-temperature NH3 -denitration performance of activated carbon,” no. September 2023, pp. 1–10, 2024, doi: 10.1002/clen.202300148.
[80]. S. V. Tarkar, K. Anuradha, and K. Mishra, “for pollutant removal and oil – water separation :,” pp. 18816–18858, 2026, doi: 10.1039/d6ra00055j.
[81]. H. Nguyen, Y. Wang, S. You, and H. Chao, “Insights into the mechanism of cationic dye adsorption on activated charcoal : The importance of – interactions,” Process Saf. Environ. Prot., vol. 107, pp. 168–180, 2017, doi: 10.1016/j.psep.2017.02.010.
[82]. S. Farch et al., “Application of Walnut Shell Biowaste as an Inexpensive Adsorbent for Methylene Blue Dye: Isotherms, Kinetics, Thermodynamics, and Modeling,” Sep. 2023, Vol. 10, Page 60, vol. 10, no. 1, p. 60, Jan. 2023, doi: 10.3390/SEPARATIONS10010060.
[83]. N. U. M. Nizam, M. M. Hanafiah, E. Mahmoudi, A. A. Halim, and A. W. Mohammad, “The removal of anionic and cationic dyes from an aqueous solution using biomass-based activated carbon,” Sci. Rep., vol. 11, no. 1, pp. 1–17, Dec. 2021, doi: 10.1038/S41598-021-88084-Z;SUBJMETA=169,172,704;KWRD=ENVIRONMENTAL+CHEMISTRY,ENVIRONMENTAL+SCIENCES.
[84]. B. Kocabiyik and Y. Bayrak, “Application of a Bio-waste Einkorn (Triticum monococcum L.) Husks Adsorbent for Removal of Metanil Yellow and Methylene Blue from Aqueous Media with Equilibrium, Kinetic, and Thermodynamic Studies,” Water. Air. Soil Pollut., vol. 235, no. 3, pp. 1–21, 2024, doi: 10.1007/s11270-024-06996-8.
[85]. L. Luo et al., “Synthesis of activated carbon from biowaste of fir bark for methylene blue removal,” R. Soc. Open Sci., vol. 6, no. 9, 2019, doi: 10.1098/RSOS.190523;PAGE:STRING:ARTICLE/CHAPTER.
[86]. T. Kopac and S. D. Lin, “A review on the characterization of microwave-induced biowaste-derived activated carbons for dye adsorption,” Int. J. Environ. Sci. Technol. 2024 2113, vol. 21, no. 13, pp. 8717–8748, Apr. 2024, doi: 10.1007/S13762-024-05583-Y.
[87]. F. Kiani Ghaleh sardi, M. Behpour, Z. Ramezani, and S. Masoum, “Simultaneous removal of Basic Blue41 and Basic Red46 dyes in binary aqueous systems via activated carbon from palm bio-waste: Optimization by central composite design, equilibrium, kinetic, and thermodynamic studies,” Environ. Technol. Innov., vol. 24, p. 102039, Nov. 2021, doi: 10.1016/J.ETI.2021.102039.
[88]. V. H. Nguyen et al., “Activated carbon with ultrahigh surface area derived from sawdust biowaste for the removal of rhodamine B in water,” Environ. Technol. Innov., vol. 24, p. 101811, Nov. 2021, doi: 10.1016/J.ETI.2021.101811.
[89]. P. Saravanan, J. Josephraj, B. P. Thillainayagam, and G. Ravindiran, “Evaluation of the adsorptive removal of cationic dyes by greening biochar derived from agricultural bio-waste of rice husk,” Biomass Convers. Biorefinery, vol. 13, no. 5, pp. 4047–4060, Apr. 2023, doi: 10.1007/S13399-021-01415-Y/FIGURES/18.
[90]. W. Astuti et al., “Influence of lignocellulosic composition in biomass waste on the microstructure and dye adsorption characteristics of microwave-assisted ZnCl2 activated carbon,” Biomass Convers. Biorefinery, vol. 14, no. 14, pp. 16681–16697, 2024, doi: 10.1007/s13399-023-04281-y.
[91]. B. Krishnappa et al., “Biowaste-Derived, Highly Efficient, Reusable Carbon Nanospheres for Speedy Removal of Organic Dyes from Aqueous Solutions,” Molecules, vol. 27, no. 20, p. 7017, Oct. 2022, doi: 10.3390/MOLECULES27207017/S1.
[92]. D. Paluch, A. Bazan-Wozniak, A. Nosal-Wiercińska, and R. Pietrzak, “Efficient dye removal by biocarbon obtained by chemical recycling of waste from the herbal industry,” Ind. Crops Prod., vol. 220, p. 119254, Nov. 2024, doi: 10.1016/J.INDCROP.2024.119254.
[93]. C. H. Pimentel, M. S. Freire, D. Gómez-Díaz, and J. González-Álvarez, “Preparation of activated carbon from pine (Pinus radiata) sawdust by chemical activation with zinc chloride for wood dye adsorption,” Biomass Convers. Biorefinery, vol. 13, no. 18, pp. 16537–16555, Dec. 2023, doi: 10.1007/S13399-023-04138-4/TABLES/1.
[94]. M. N. Al-leithy and A. M. Shater, “Monitoring of soil pollution with heavy metals using some microbiological parameters,” Egypt. J. Basic Appl. Sci., vol. 11, no. 1, pp. 584–601, 2024, doi: 10.1080/2314808X.2024.2369821.
[95]. M. H. Al-malack and A. A. Basaleh, “Adsorption of heavy metals using activated carbon produced from municipal organic solid waste,” Desalin. Water Treat., vol. 57, no. 51, pp. 24519–24531, 2016, doi: 10.1080/19443994.2016.1144536.
[96]. H. Dhila, A. Bhapkar, and S. Bhame, “Metal oxide / biochar hybrid nanocomposites for adsorption and photocatalytic degradation of textile dye effluents : A review,” Desalin. Water Treat., vol. 321, no. August 2024, p. 101004, 2025, doi: 10.1016/j.dwt.2025.101004.
[97]. S. Kulbir, W. S. Abdullahi, and R. Chhotu, “Removal of Heavy Metals by Adsorption using Agricultural based Residue: A Removal of Heavy Metals by Adsorption using Agricultural based Residue: A Review,” no. September, 2018.
[98]. H. Lin, J. Xie, Y. Dong, J. Liu, K. Meng, and Q. Jin, “Journal of Environmental Chemical Engineering A complete review on the surface functional groups in pyrolyzed biochar and its interaction mechanism with heavy metal in water,” J. Environ. Chem. Eng., vol. 13, no. 3, p. 116681, 2025, doi: 10.1016/j.jece.2025.116681.
[99]. J. Bayuo, M. Rwiza, and K. Mtei, Response surface optimization and modeling in heavy metal removal from wastewater — a critical review. Springer International Publishing, 2022. doi: 10.1007/s10661-022-09994-7.
[100]. H. Bassareh, M. Karamzadeh, and S. Movahedirad, “Synthesis and characterization of cost ‑ effective and high ‑ efficiency biochar for the adsorption of from wastewater,” Sci. Rep., pp. 1–15, 2023, doi: 10.1038/s41598-023-42918-0.
[101]. B. Wang, J. Lan, and C. Bo, “RSC Advances Adsorption of heavy metal onto biomass-derived activated carbon: review,” RSC Adv., vol. 13, pp. 4275–4302, 2023, doi: 10.1039/D2RA07911A.
[102]. J. I. Lingkungan, V. Rofikoh, B. Zaman, and B. P. Samadikun, “The Potential of Commercial Biomass-Based Activated Carbon to Remove Heavy Metals in Wastewater – A Review,” vol. 22, no. 1, pp. 132–141, 2024, doi: 10.14710/jil.22.1.132-141.132.
[103]. M. Islam, A. A. Mohana, A. Rahman, M. Rahman, R. Naidu, and M. M. Rahman, “A Comprehensive Review of the Current Progress of Chromium Removal Methods from Aqueous Solution,” pp. 1–43, 2023, doi: https://doi.org/10.3390/toxics11030252.
[104]. W. Tang, N. Cai, H. Xie, Y. Liu, and Z. Wang, “Efficient adsorption removal of Cd 2 + from aqueous solutions by HNO3 modified bamboo-derived biochar Efficient adsorption removal of Cd 2 + from aqueous solutions by HNO 3 modified bamboo-derived biochar,” pp. 0–10, 2020, doi: 10.1088/1757-899X/729/1/012081.
[105]. H. Kumar, J. Mahesh, C. Vishwakarma, R. Kumar, H. Sharma, and S. Kumar, “Adsorption of Cd 2 + from synthetic wastewater by modified leaves of Eupatorium adenophorum and Acer oblongum: thermodynamics , kinetics and equilibrium studies,” Discov. Water, 2022, doi: 10.1007/s43832-022-00018-6.
[106]. S. H. A. Hassan, M. M. Alomran, N. I. A. Alsugiran, M. Koutb, H. Ahmed, and M. A. Fawzy, “Response surface optimization for cadmium biosorption onto the pre-treated biomass of red algae Digenia simplex as a sustainable indigenous biosorbent,” 2025, doi: 10.7717/peerj.19776.
[107]. I. Rahman, C. Shakhawat, M. Abu, J. Mazumder, and A. Al Ahmed, Removal of lead ions ( Pb 2 + ) from water and wastewater: a review on the low ‑ cost adsorbents, vol. 12, no. 8. Springer International Publishing, 2022. doi: 10.1007/s13201-022-01703-6.
[108]. U. Fernando, C. Sayago, V. B. Ballesteros, and A. M. Lozano, “Design of Biomass Adsorbents Based on Bacterial Cellulose and E. crassipes for the Removal of Cr (VI),” no. Vi, 2025, doi: https://doi.org/10.3390/polym17121712.
[109]. F. Chen, Y. Sun, C. Liang, T. Yang, S. Mi, and Y. Dai, “Adsorption characteristics and mechanisms of from aqueous solution by biochar derived from corn stover,” Sci. Rep., no. 0123456789, pp. 1–17, 2022, doi: 10.1038/s41598-022-22714-y.
[110]. O. I. Adeiga and K. Pillay, “Adsorptive Removal of Cd ( II ) Ions from Water by a Cheap Lignocellulosic Adsorbent and Its Reuse as a Catalyst for the Decontamination of Sulfamethoxazole,” no. Ii, 2024, doi: 10.1021/acsomega.3c08761.
[111]. M. A. El et al., “Adsorption of Cr 6 + ion using activated Pisum sativum peels ‑ triethylenetetramine,” pp. 91036–91060, 2022, doi: 10.1007/s11356-022-21957-6.
[112]. A. Singh, S. Kumar, and V. Panghal, “Adsorption of chromium ( Cr 6 + ) on dead biomass of Salvinia molesta ( Kariba weed ) and Typha latifolia ( broadleaf cattail ): isotherm , kinetic , and thermodynamic study,” Appl. Water Sci., vol. 11, no. 9, pp. 1–16, 2021, doi: 10.1007/s13201-021-01481-7.
[113]. L. C. B. A. Review, R. Das, S. Saha, and G. R. Mahapatra, “Removal of Hexavalent Chromium Ion ( Cr6 + ) From Industrial Effluents Using Removal of Hexavalent Chromium Ion ( Cr 6 + ) From Industrial Effluents Using Low Cost Bio-Adsorbents: A Review Abstract:,” no. February, 2023, doi: 10.5281/zenodo.7777253.
[114]. A. Ojha, D. Tiwary, R. Oraon, and P. Singh, “Degradations of endocrine-disrupting chemicals and pharmaceutical compounds in wastewater with carbon-based nanomaterials: a critical review,” pp. 30573–30594, 2021, doi: https://doi.org/10.1007/s11356-021-13939-x.
[115]. V. Rac, M. Krmar, O. Otman, and A. Auroux, “The adsorption of pharmaceutically active compounds from aqueous solutions onto activated carbons,” vol. 282, pp. 141–149, 2015, doi: 10.1016/j.jhazmat.2014.04.062.
[116]. M. Boshir, J. L. Zhou, H. H. Ngo, A. Hasan, and L. Sun, “Sorption of hydrophobic organic contaminants on functionalized biochar: Protagonist role of π - π electron-donor-acceptor interactions and hydrogen bonds,” J. Hazard. Mater., vol. 360, no. August, pp. 270–278, 2018, doi: 10.1016/j.jhazmat.2018.08.005.
[117]. Z. Uba, Z. Kuan, S. Khoo, A. Garba, and M. Abubakar, A review on carbon ‑ based biowaste and organic polymer materials for sustainable treatment of sulfonamides from pharmaceutical wastewater, vol. 46, no. 4. Springer Netherlands, 2024. doi: 10.1007/s10653-024-01936-1.
[118]. F. A. Ahmad, “Heliyon The use of agro-waste-based adsorbents as sustainable, renewable, and low-cost alternatives for the removal of ibuprofen and carbamazepine from water,” Heliyon, vol. 9, no. 6, p. e16449, 2025, doi: 10.1016/j.heliyon.2023.e16449.
[119]. A. M. Aljeboree, “Adsorption of Pharmaceuticals as emerging contaminants from aqueous solutions on to friendly surfaces such as activated carbon: A review,” vol. 10, no. 9, pp. 2252–2257, 2018.
[120]. J. F. a Bingyuan Huang a, Dan Huang b, Qian Zheng a, Changhan Yan a, “Enhanced adsorption capacity of tetracycline on porous graphitic biochar with an ultra-large surface area,” 2023, doi: https://doi.org/10.1039/d3ra00745f.
[121]. A. O. Arinkoola, “Adsorptive Removal of Ibuprofen, Ketoprofen and Naproxen from Aqueous Solution Using Coconut,” pp. 28–37, 2022, doi: 10.5755/j01.erem.78.2.29695.
[122]. R. Baccar, M. Sarrà, J. Bouzid, M. Feki, and P. Blánquez, “Removal of pharmaceutical compounds by activated carbon prepared from agricultural by-product,” Chem. Eng. J., vol. 211–212, no. 2012, pp. 310–317, 2013, doi: 10.1016/j.cej.2012.09.099.
[123]. S. Minaei, K. Zoroufchi, K. N. Mcphedran, and J. Soltan, “Adsorption of sulfamethoxazole and lincomycin from single and binary aqueous systems using acid-modified biochar from activated sludge biomass,” J. Environ. Manage., vol. 358, no. April, p. 120742, 2024, doi: 10.1016/j.jenvman.2024.120742.
[124]. M. O. Omorogie et al., “Microwave-synthesized and Fenton-functionalized Pinus sylvestris bark activated carbon / metal oxides for the effective uptake of tetracycline and congo red dye,” 2019, doi: https://doi.org/10.1007/s13399-019-00460-y.
[125]. Y. B. Nthwane, B. G. Fouda-Mbanga, M. Thwala, and K. Pillay, “A comprehensive review of heavy metals (Pb2+, Cd2+, Ni2+) removal from wastewater using low-cost adsorbents and possible revalorisation of spent adsorbents in blood fingerprint application,” Environ. Technol. (United Kingdom), vol. 46, no. 3, pp. 414–430, 2025, doi: 10.1080/09593330.2024.2358450.
[126]. J. Wu, X. Sun, J. Wu, and X. Yu, “Eggshell-enhanced biochar with in-situ formed CaO/Ca(OH)2 for efficient removal of Pb2+ and Cd2+ from wastewater: Performance and mechanistic insights,” Sep. Purif. Technol., vol. 354, p. 129352, Feb. 2025, doi: 10.1016/J.SEPPUR.2024.129352.
[127]. M. A. Abu-Daabes, E. Abu Zeitoun, and W. Mazi, “Competitive Adsorption of Quaternary Metal Ions, Ni2+, Mn2+, Cr6+, and Cd2+, on Acid-Treated Activated Carbon,” Water 2023, Vol. 15, Page 1070, vol. 15, no. 6, p. 1070, Mar. 2023, doi: 10.3390/W15061070.
[128]. A. A. Abd, M. R. Othman, and J. Kim, “A review on application of activated carbons for carbon dioxide capture: present performance, preparation, and surface modification for further improvement,” Environ. Sci. Pollut. Res. 2021 2832, vol. 28, no. 32, pp. 43329–43364, Jun. 2021, doi: 10.1007/S11356-021-15121-9.
[129]. H. Ben Slama et al., “Diversity of Synthetic Dyes from Textile Industries, Discharge Impacts and Treatment Methods,” Appl. Sci. 2021, Vol. 11, Page 6255, vol. 11, no. 14, p. 6255, Jul. 2021, doi: 10.3390/APP11146255.
[130]. D. Ramutshatsha-Makhwedzha, A. Munyengabe, M. L. Mavhungu, R. Mbaya, and J. Baloyi, “Breakthrough studies for the sorption of methylene blue dye from wastewater samples using activated carbon derived from waste banana peels,” Biomass Convers. Biorefinery, vol. 14, no. 18, pp. 21757–21769, Sep. 2024, doi: 10.1007/S13399-023-04329-Z/FIGURES/2.
[131]. E. Loffredo, “Recent Advances on Innovative Materials from Biowaste Recycling for the Removal of Environmental Estrogens from Water and Soil,” Mater. 2022, Vol. 15, Page 1894, vol. 15, no. 5, p. 1894, Mar. 2022, doi: 10.3390/MA15051894.
[132]. C. E. Almeida-Naranjo, J. Tejedor, C. A. Villamar-Ayala, and G. Vizuete, “Transforming waste into solutions: Raw and modified bioadsorbents for emerging contaminant removal,” J. Environ. Chem. Eng., vol. 13, no. 3, p. 116720, 2025, doi: 10.1016/j.jece.2025.116720.
[133]. K. Malini, D. Selvakumar, and N. S. Kumar, “Activated carbon from biomass: Preparation, factors improving basicity and surface properties for enhanced CO2 capture capacity – A review,” J. CO2 Util., vol. 67, p. 102318, Jan. 2023, doi: 10.1016/J.JCOU.2022.102318.
[134]. A. Mukherjee, B. Saha, C. Niu, and A. K. Dalai, “Preparation of activated carbon from spent coffee grounds and functionalization by deep eutectic solvent: Effect of textural properties and surface chemistry on CO2 capture performance,” J. Environ. Chem. Eng., vol. 10, no. 6, p. 108815, Dec. 2022, doi: 10.1016/J.JECE.2022.108815.
[135]. L. Fang, C. Xu, J. Li, O. K. Borggaard, and D. Wang, “The importance of environmental factors and matrices in the adsorption, desorption, and toxicity of butyltins: a review,” Environ. Sci. Pollut. Res., vol. 24, no. 10, pp. 9159–9173, Apr. 2017, doi: 10.1007/S11356-017-8449-Z/METRICS.
[136]. I. M. Lima et al., “Design and Operation of a Scaled-up Pilot Plant for the Removal of Sugar Beet Extract Colorants using Powdered Activated Carbon,” Sugar Tech, vol. 23, no. 1, pp. 167–177, 2021, doi: 10.1007/s12355-020-00812-3.
[137]. “The production cost analysis of oil palm waste activated carbon : a pilot-scale evaluation,” vol. 1026, pp. 999–1026, 2020, doi: 10.1002/ghg.2020.
[138]. M. Raninga, A. Mudgal, V. K. Patel, J. Patel, and M. Kumar Sinha, “Modification of activated carbon-based adsorbent for removal of industrial dyes and heavy metals: A review,” Mater. Today Proc., vol. 77, pp. 286–294, Jan. 2023, doi: 10.1016/J.MATPR.2022.11.358.
[139]. R. Devi et al., “Recent advancement in biomass-derived activated carbon for waste water treatment, energy storage, and gas purification: a review,” J. Mater. Sci. 2023 5830, vol. 58, no. 30, pp. 12119–12142, Aug. 2023, doi: 10.1007/S10853-023-08773-0.
[140]. H. Supercapacitors, Y. Wang, J. Wang, X. Zhang, D. Bhattacharyya, and E. M. Sabolsky, “Quantifying Environmental and Economic Impacts of Highly Porous Activated Carbon from Lignocellulosic Biomass for,” 2022.
[141]. S. Yadav, N. Sharma, A. Dalal, and P. Panghal, Cutting ‑ edge regeneration technologies for saturated adsorbents : a systematic review on pathways to circular wastewater treatment system. Springer International Publishing, 2025. doi: 10.1007/s10661-025-13657-8.
[142]. L. Liu et al., “Bioresource Technology Techno-economic analysis of biomass processing with dual outputs of energy and activated carbon,” Bioresour. Technol., vol. 319, no. September 2020, p. 124108, 2021, doi: 10.1016/j.biortech.2020.124108.
[143]. L. Gazigil, E. Er, and T. Yonar, “Determination of the optimum conditions for electrochemical regeneration of exhausted activated carbon,” Diam. Relat. Mater., vol. 133, no. January, p. 109741, 2023, doi: 10.1016/j.diamond.2023.109741.
[144]. S. T. Tibor and C. A. Grande, “Industrial production of activated carbon using circular bioeconomy principles: Case study from a Romanian company,” Clean. Eng. Technol., vol. 7, p. 100443, Apr. 2022, doi: 10.1016/J.CLET.2022.100443.








