Published
2020-11-04
Issue
Section
Original Research Article
License
The Author(s) warrant that permission to publish the article has not been previously assigned elsewhere.
Author(s) shall retain the copyright of their work and grant the Journal/Publisher right for the first publication with the work simultaneously licensed under:
OA - Creative Commons Attribution-NonCommercial 4.0 International (CC BY-NC 4.0). This license allows for the copying, distribution and transmission of the work, provided the correct attribution of the original creator is stated. Adaptation and remixing are also permitted.
This license intends to facilitate free access to, as well as the unrestricted reuse of, original works of all types for non-commercial purposes.
How to Cite
Synthesis and characterization of nickel oxide and evaluation of its catalytic activities for degradation of methyl orange in aqueous medium
Muhammad Saeed
Department of Chemistry, Government College University Faisalabad
Muhammad Amjed
Department of Chemistry, Government College University Faisalabad
Attaul Haq
Department of Chemistry, Government College University Faisalabad
Muhammad Usman
Department of Chemistry, Government College University Faisalabad
Shahid Adeel
Department of Chemistry, Government College University Faisalabad
DOI: https://doi.org/10.24294/ace.v3i2.737
Keywords: Nickel Oxide, Methyl Orange, Degradation, Eley-Rideal Mechanism
Abstract
This study focuses on synthesis of nickel oxide catalyst and exploration of its catalytic activities for degradation of methyl orange in aqueous medium. Nickel oxide was prepared sole-gel method using nickel nitrate haxahydrate and citric acid as precursor materials. X-ray diffractometry and scanning electron microscopy were used for characterization of prepared nickel oxide particles. The prepared particles were used as the catalysts for the degradation of Methyl Orange in aqueous medium. The effects of different parameters on degradation of methyl orange were investigated. The degradation of methyl orange followed the Eley-Rideal (E-R) mechanism. The apparent activation energies for degradation of methyl orange determined was found as 36.4 kJ/mol.
References
[1] Jankovi´c B, Yevi´c A, Mentus S. The kinetic study of temperature-programmed reduction of nickel oxide in hydrogen atmosphere. Chemical Engineering Science 2008; 63: 567–575.[2] Ilyas M, Saeed M. Oxidation of benzyl alcohol in liquid phase catalyzed by oxides of nickel. Journal of the Chemical Society of Pakistan 2009; 31(4): 526–533.
[3] Pacchioni G. Ab initio theory of point defects in oxide materials: Structure, properties, chemical reactivity. Solid State Sciences 2000; 2: 161–179.
[4] Liang K, Tang X, Hu W. High-performance three-dimensional nanoporous NiO film as a supercapacitor electrode. Journal of Material Chemistry 2012; 22: 11062–11067.
[5] Li X, Dhanabalan A, Wang C. Enhanced electrochemical performance of porous NiO–Ni nanocomposite anode for lithium ion batteries. Journal of Power Sources 2011; 196: 9625–9630.
[6] Jena A, Munichandraiah N, Shivashankar SA. Carbonaceous nickel oxide nano-composites: As electrode materials in electrochemical capacitor applications. Journal of Power Sources 2013; 237: 156–166.
[7] Fu X, Zhu Y, Xu Q, et al. Nickel oxyhydroxides with various oxidation states prepared by chemical oxidation of spherical β-Ni(OH)2. Solid State Ionics 2007; 178: 987–993.
[8] Soleimanpour AM, Jayatissa AH. Preparation of nanocrystalline nickel oxide thin films by sol–gel process for hydrogen sensor applications. Materials Science and Engineering C 2012; 32: 2230–2234.
[9] Nakagawa K, Konaka R, Nakata T. Oxidation with nickel peroxide. I. oxidation of alcohols. Journal of Organic Chemistry 1962; 27(5): 1597–1601.
[10] Konaka R, Terabe S, Kuruma K. Mechanism of the oxidation reaction with nickel peroxide. Journal of Organic Chemistry 1969; 34(5): 1334–1337.
[11] Fleischmann M, Korinek K, Pletcher D. The kinetics and mechanism of the oxidation of amines and alcohols at oxide-covered nickel, silver, copper, and cobalt electrodes. Journal of Chemical Society PerkinTransaction 1972; 2: 1396–1403.
[12] Atiq S, Javid M, Riaz S, et al. Magnetic phase transition in nickel oxide. Materials Today: Proceedings 2015; 2(10): 5262–5267.
[13] Saeed M, Ilyas M, Siddique M. Kinetics of lab prepared manganese oxide catalyzed oxidation of benzyl alcohol in the liquid phase. International Journal of Chemical Kinetics 2015; 47(7): 447–460.
[14] Saeed M, Ilyas M. Oxidative removal of phenol from water catalyzed by lab prepared nickel hydroxide. Applied Catalysis B Environmental 2013; 129(1): 247–254.
[15] Saeed M, Ilyas M, Siddique M. Oxidative degradation of oxalic acid in aqueous medium using manganese oxide as catalyst at ambient temperature and pressure. Arabian Journal for Science & Engineering 2013; 38: 1739–1748.
[16] Saeed M, Ilyas M, Siddique M. Oxidative degradation of phenol in aqueous medium catalyzed by lab prepared cobalt oxide. Journal of the Chemical Society of Pakistan 2012; 34(3): 626–633.
[17] Saeed M, Adeel S, Ilyas M, et al. Oxidative degradation of methyl orange catalyzed by lab prepared nickel hydroxide in aqueous medium. Desalination and Water Treatment 2016; 57(27): 12804–12813.